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Theoretical analysis of spin crossover in iron(II) [2×2] molecular grids

Ekaterina M Zueva1, Elmira R Ryabikh, Serguei A Borshch

  • 1Department of Inorganic Chemistry, Kazan State Technological University, 68 K. Marx Street, 420015 Kazan, Russia. zueva_ekaterina@mail.ru

Inorganic Chemistry
|October 15, 2011
PubMed
Summary

Spin-crossover in iron(II) molecular grids is influenced by ligand elasticity and neighboring spin states. Structural distortions dictate spin transition pathways, tunable by minor perturbations like hydrogen atom shifts.

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