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Updated: May 28, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
"Governing initiation-supporting termination" in chiral poly(n-hexyl isocyanate)
Priyank N Shah1, Joonkeun Min, Jae-Suk Lee
1Department of Nanobio Materials and Electronics and School of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123 Cheomdan-gwagiro (1 Oryong-dong), Buk-gu, Gwangju 500712, Republic of Korea.
Abstract:
Poly(n-hexyl isocyanate) (PHIC) with varying molecular weights were synthesized using a chiral initiator and chiral terminator by living anionic polymerization. In such PHICs, chirality of the initiator plays a decisive role in determining the helical sense of the entire polymeric chain, whereas chirality of the terminator plays a supportive role.
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