Polymeric structure of oxalato-bridged complexes of tetravalent actinides Th, U, Np and Pu
Grigory Andreev1, Nina Budantseva, Aleksander Fedoseev
1Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, 31 Leninskiy pr., Moscow, 119991, Russia. grigory_andreev@mail.ru
Abstract:
A series of isostructural oxalates of Th, U, Np, and Pu have been synthesized. The crystal structure of {C(NH(2))(3)}(4)[An(C(2)O(4))(4)]·2H(2)O comprises infinite [An(C(2)O(4))(4)](4n-) chains, guanidinium cations and water molecules. Each An atom is connected to five oxalate anions, two of which act as bridging tetradentate ligands, while the other three function as terminating bidentate ligands. Electron and IR spectra of the compounds as well as the results of thermal analysis correlate with their structure. An actinide contraction effect is demonstrated by a decrease in the An-O interatomic distances and the volumes of An atom coordination polyhedra and Voronoi-Dirichlet polyhedra. Ten-coordinate An oxalates are discussed in terms of continuous shape measures approach.
Related Concept Videos
Valence Bond Theory
Coordination Compounds and Nomenclature
EDTA: Chemistry and Properties
Complexometric Titration: Ligands
Coordination Number and Geometry
Complexation Equilibria: The Chelate Effect

