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Phosphorus removal using nanofiltration membranes.

C P Leo1, W K Chai, A W Mohammad

  • 1School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia Seri Ampangan, 14300 Nibong Tebal, Penang, Malaysia. chcpleo@eng.usm.my

Water Science and Technology : a Journal of the International Association on Water Pollution Research
|November 8, 2011
PubMed
Summary
This summary is machine-generated.

Nanofiltration effectively removes phosphorus from wastewater, with NF90 membranes showing over 70% rejection. Optimizing pH and avoiding acetic acid are key for efficient phosphorus recovery.

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Area of Science:

  • Environmental Science
  • Water Treatment Technologies
  • Chemical Engineering

Background:

  • High phosphorus concentrations in wastewater cause eutrophication and deoxygenation.
  • Phosphorus removal and recycling are critical for environmental protection and resource recovery.

Purpose of the Study:

  • To investigate the potential of nanofiltration (NF) for removing and recycling phosphorus from wastewater.
  • To characterize and test commercial NF membranes for phosphorus-rich solutions.

Main Methods:

  • Analysis of pulp and paper plant wastewater.
  • Characterization and performance testing of commercial NF membranes (DK5, MPF34, NF90, NF270, NF200).
  • Experiments focused on membrane permeability and phosphorus removal efficiency at varying conditions.

Main Results:

  • NF90 membranes demonstrated the highest phosphorus rejection (>70%) at pH <2 with a feed concentration of 2.5 g/L.
  • NF90, NF200, and NF270 membranes exhibited higher permeability than DK5 and MPF34.
  • NF90 performance was sensitive to concentration polarization and fouling, but improved at pH 2 or with sulfuric acid addition.
  • Acetic acid significantly reduced phosphorus rejection.

Conclusions:

  • Nanofiltration, particularly using NF90 membranes, is a viable technology for phosphorus removal and potential recycling from industrial wastewater.
  • Optimizing operational parameters like pH and avoiding specific chemical inhibitors (e.g., acetic acid) is crucial for maximizing NF efficiency in phosphorus removal.