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Related Experiment Video

Updated: May 27, 2026

Indirect Fabrication of Lattice Metals with Thin Sections Using Centrifugal Casting

Indirect Fabrication of Lattice Metals with Thin Sections Using Centrifugal Casting

Published on: May 14, 2016

Anisotropic two-dimensional sheets assembled from rod-shaped metal complexes.

Mina Han¹, Tomohiro Hirade

¹Department of Chemistry, Tokyo Institute of Technology, Yokohama 226-8502, Japan. han.m.ab@m.titech.ac.jp

Chemical Communications (Cambridge, England)

|November 8, 2011

Summary

Researchers easily created anisotropic two-dimensional sheets using rod-shaped palladium complexes. These sheets varied in size from the nanometre to micrometre scale, demonstrating controlled assembly.

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Indirect Fabrication of Lattice Metals with Thin Sections Using Centrifugal Casting

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Published on: May 14, 2016

Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets

Solid-phase Submonomer Synthesis of Peptoid Polymers and their Self-Assembly into Highly-Ordered Nanosheets

Published on: November 2, 2011

Area of Science:

Materials Science
Nanotechnology
Supramolecular Chemistry

Background:

Two-dimensional (2D) materials offer unique properties due to their reduced dimensionality.
Controlling the size and anisotropy of 2D materials is crucial for tailored applications.
Self-assembly of metal complexes provides a versatile route to ordered nanostructures.

Purpose of the Study:

To develop a facile method for synthesizing anisotropic 2D sheets.
To control the size of these sheets across the nano- and micro-scale.
To investigate the self-assembly behavior of rod-shaped palladium complexes.

Main Methods:

Utilizing rod-shaped palladium complexes as building blocks.
Employing self-assembly processes to form 2D structures.
Characterizing the size and morphology of the resulting sheets using microscopy techniques.

Main Results:

Achieved facile formation of anisotropic 2D sheets.
Demonstrated control over sheet sizes, ranging from nanometre-scale to micrometre-scale.
Confirmed the assembly of rod-shaped palladium complexes into sheet structures.

Conclusions:

Rod-shaped palladium complexes self-assemble into anisotropic 2D sheets.
The assembly process allows for tunable control over sheet dimensions.
This method offers a promising approach for fabricating size-controlled 2D nanomaterials.