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Highly twisted arenes by Scholl cyclizations with unexpected regioselectivity

Anirban Pradhan1, Pierre Dechambenoit, Harald Bock

  • 1Centre de Recherche Paul Pascal, CNRS & Université de Bordeaux, 115 Avenue Schweitzer, 33600 Pessac, France.

Angewandte Chemie (International Ed. in English)
|November 8, 2011
PubMed
Summary

The Scholl reaction readily forms twisted polycyclic aromatic hydrocarbons, even with bulky groups. This method efficiently synthesizes complex helicene structures from simple precursors.

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