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Updated: May 27, 2026

19:58
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
{N,N-Bis[2-(diphenyl-phosphan-yl)eth-yl]-aniline}(η-dibenzyl-ideneacetone)-palladium(0)
Seyma Gören Keskin1, Julie M Stanley, Michelle L Mejía
1Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station, A5300, Austin, Texas 78712, USA.
Acta Crystallographica. Section E, Structure Reports Online
|November 9, 2011
Abstract:
In the title complex, [Pd(C(34)H(33)NP(2))(C(17)H(14)O)], the Pd(0) atom is coordinated in a trigonal planar geometry formed by two P atoms of a bis-[(diphenyl-phosphino)eth-yl]aniline ligand and a C=C (η(2)) bond involving the C atoms that are in the α,β positions relative to the central ketone of the dibenzyl-ideneacetone ligand.
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
