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Updated: May 27, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
1-[(E)-4-(Phenyl-diazen-yl)phen-yl]-3-pyrroline-2,5-dione
Abstract:
The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The mol-ecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with respect to the azo group mean plane, which, in turn, forms a dihedral angle of 24.48 (7)° with the 'terminal' benzene ring. Mol-ecules in the crystal are π-π stacked along the [100] direction with a mean inter-planar distance of 3.857 (1) Å. In addition, C-H⋯O inter-actions link them into double layers parallel to the ac plane.
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