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Silylium-arene adducts: an experimental and theoretical study

Muhammad Farooq Ibad1, Peter Langer, Axel Schulz

  • 1Abteilung Anorganische Chemie, Institut für Chemie, Universität Rostock, Albert-Einstein-Strasse 3a, D-18059 Rostock, Germany.

Journal of the American Chemical Society
|November 17, 2011
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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