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Updated: May 27, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Bis(acetonitrile-κN)dichlorido(η-cyclo-octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
Abstract:
In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol-ecule per mol-ecule which is outside the coordination sphere of the ruthenium atom.
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