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Updated: May 27, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(E)-2-(2-Formyl-phen-oxy-meth-yl)-3-phenyl-prop-2-ene-nitrile
Acta Crystallographica. Section E, Structure Reports Online
|November 18, 2011
Summary
This study details the crystal structure of a novel organic compound, C(17)H(13)NO(2). Key findings include the dihedral angle between its rings and the near-linear carbonitrile group, stabilized by C-H⋯O interactions.
Area of Science:
- Crystallography
- Organic Chemistry
- Materials Science
Background:
- Understanding the three-dimensional arrangement of atoms in organic molecules is crucial for predicting their properties.
- The specific compound C(17)H(13)NO(2) presents an interesting structural motif for investigation.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(17)H(13)NO(2).
- To analyze the molecular geometry, including ring orientation and functional group linearity.
- To identify the intermolecular forces stabilizing the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and dihedral angles was performed.
- Identification of intermolecular interactions, such as hydrogen bonds and van der Waals forces, was conducted.
Main Results:
- The dihedral angle between the benzene and phenyl rings was determined to be 65.92(7)°.
- The carbonitrile side chain exhibited a near-linear geometry, with a C-C-N angle of 175.55(14)°.
- The crystal structure is stabilized by intermolecular C-H⋯O interactions.
Conclusions:
- The study successfully characterized the crystal structure of C(17)H(13)NO(2).
- The observed molecular geometry and intermolecular interactions provide insights into the compound's solid-state behavior.
- This structural information can guide future research on related compounds and their applications.
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