1,5-Anhydro-2-de-oxy-1,2-C-dichloro-methyl-ene-3,4,6-tri-O-(4-meth-oxy-benz-yl)-d-glycero-d-gulo-hexitol
Henok H Kinfe1, Paseka T Moshapo, Alfred Muller
1Research Center in Synthesis and Catalysis, Department of Chemistry, University of Johannesburg (APK Campus), PO Box 524, Auckland Park, Johannesburg 2006, South Africa.
Abstract:
The pyranosyl ring in the title compound, C(31)H(34)Cl(2)O(7), adopts a twist-boat conformation. The 4-meth-oxy-benzyl groups are located in equatorial positions with the meth-oxy groups nearly coplanar with their respective rings [dihedral angles of 0.2 (3) and 9.4 (2)°]. The aromatic rings adopt orientations enabling them to participate in C-H⋯π inter-actions with neighboring meth-oxy groups. The crystal structure is additionally stabilized by weak C-H⋯O inter-actions.
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