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Updated: May 27, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(4R,11R)-9-(1-hydroxypropan-2-yl)-4,11-diphenyl-1,3,5,7,9-pentaazatri-cyclo[5.3.1.0]undecane-2,6-dithione
Meng Wang1, Jungang Wang, Jiacheng Xiang
1Key Laboratory of Pesticide and Chemical Biology of the Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
Abstract:
The asymmetric unit of the title compound, C(21)H(23)N(5)OS(2), contains two independent chiral mol-ecules. The two phenyl rings of one mol-ecule form a dihedral angle of 51.95 (7)° and the distance between their centroids is 4.345 (1) Å. In the other mol-ecule, the phenyl rings form a dihedral angle of 58.79 (8)° with a ring centroid-centroid distance of 4.435 (2) Å. An intra-molecular O-H⋯N hydrogen bond occurs in each independent mol-ecule. The crystal packing is stabilized by and inter-molecular N-H⋯O and N-H⋯S hydrogen bonds and C-H⋯S inter-actions.
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