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Updated: May 27, 2026

09:22
Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Columnar self-assembly of rhomboid macrocyclic molecules via step-like intermolecular interaction. Crystal formation
Tomohito Ide1, Daisuke Takeuchi, Kohtaro Osakada
1Chemical Resources Laboratory, Tokyo Institute of Technology, 4359 Nagatsuda, Yokohama 226-8503, Japan.
Abstract:
Two macrocyclic compounds with a rhomboid molecular shape, composed of a π-conjugated framework and an imine or amine functionality, were synthesized. The amine-containing macrocycle crystallizes with step-like interaction of each molecule, forming a columnar arrangement, although dispersion of the imine gelates upon ultrasonification.
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