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Regioselectivity of H cluster oxidation

Marta K Bruska1, Martin T Stiebritz, Markus Reiher

  • 1Laboratorium für Physikalische Chemie, ETH Zurich, Wolfgang-Pauli-Strasse 10 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|November 24, 2011
PubMed
Summary

[FeFe] hydrogenases are sensitive to oxygen, limiting their H(2) production. This study reveals how oxygen damages the enzyme's active site, explaining its irreversible inhibition.

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