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Related Concept Videos

Entropy Changes Accompanying Specific Processes01:21

Entropy Changes Accompanying Specific Processes

Entropy, a measure of disorder in a system, changes during phase transitions like freezing or boiling. At the transition temperature Ttrs, where two phases are in equilibrium, the phase transition is a reversible process. The entropy change can be calculated from a substance's enthalpy of transition using the equation ΔStrs = ΔtrsH /Ttrs.When a perfect gas expands isothermally from one volume to another, entropy increases logarithmically with volume. Conversely, isothermal compression results...
Entropy Change in Reversible Processes01:10

Entropy Change in Reversible Processes

In the Carnot engine, which achieves the maximum efficiency between two reservoirs of fixed temperatures, the total change in entropy is zero. The observation can be generalized by considering any reversible cyclic process consisting of many Carnot cycles. Thus, it can be stated that the total entropy change of any ideal reversible cycle is zero.
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Phase Transitions02:31

Phase Transitions

Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to occupy...
Phase Transitions01:21

Phase Transitions

A phase transition is the process in which a substance changes from one state of matter to another, like from a solid to a liquid, liquid to gas, or vice versa, at a specific temperature and under given pressure conditions. This change is spontaneous and is affected by alterations in temperature and pressure. These parameters impact the strength of the forces between molecules (intermolecular forces) in the substance.During a phase transition, both the initial and final phases of the substance...
Transition State Theory01:25

Transition State Theory

Transition-state theory, also known as activated-complex theory, provides a molecular-level explanation of reaction rates in both gas-phase and solution-phase reactions. It extends earlier kinetic models by considering the formation of a short-lived, high-energy configuration during a reaction.The progress of a chemical reaction can be represented using a reaction profile, which plots potential energy against the reaction coordinate. As two reactant molecules approach one another, their...
Deactivation Processes: Jablonski Diagram01:25

Deactivation Processes: Jablonski Diagram

Luminescence, the emission of light by a substance that has absorbed energy, is a process that involves the interaction of molecules with light. The energy-level diagram, or Jablonski diagram, is a graphical representation of these interactions, illustrating the various states and transitions a molecule can undergo. In a typical Jablonski diagram, the lowest horizontal line represents the ground-state energy of the molecule, which is usually a singlet state. This state represents the energies...

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Related Experiment Video

Updated: May 27, 2026

Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform
05:39

Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform

Published on: August 2, 2019

Environment-induced sudden transition in quantum discord dynamics.

R Auccaise1, L C Céleri, D O Soares-Pinto

  • 1Empresa Brasileira de Pesquisa Agropecuária, Rua Jardim Botânico 1024, 22460-000 Rio de Janeiro, Rio de Janeiro, Brazil.

Physical Review Letters
|November 24, 2011
PubMed
Summary

Researchers explored quantum discord in a nuclear magnetic resonance setup. They observed sudden changes and noise immunity in quantum correlations, even in separable states, highlighting their importance in quantum information science.

Related Experiment Videos

Last Updated: May 27, 2026

Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform
05:39

Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform

Published on: August 2, 2019

Area of Science:

  • Quantum Information Science
  • Quantum Correlation Dynamics

Background:

  • Nonclassical correlations are vital for quantum information science.
  • Separable (nonentangled) quantum states can exhibit nonclassical correlations.
  • Generalized quantum correlations are relevant in quantum communication, computation, phase transitions, and biological systems.

Purpose of the Study:

  • To demonstrate the sudden-change phenomenon in quantum discord and its classical counterpart.
  • To investigate the noise resilience of quantum discord in a decohering environment.
  • To explore quantum correlation dynamics in a room-temperature nuclear magnetic resonance (NMR) system.

Main Methods:

  • Utilized a room-temperature nuclear magnetic resonance (NMR) setup.
  • Introduced a decohering environment to simulate noise effects.
  • Monitored quantum discord and its classical counterpart under decoherence.

Main Results:

  • Observed the sudden-change phenomenon for both quantum discord and its classical counterpart.
  • Demonstrated noise immunity for these quantum correlations.
  • Characterized the impact of a decohering environment, including loss of phase relations and energy exchange.

Conclusions:

  • Quantum discord and its classical counterpart exhibit sudden changes and noise resilience.
  • These generalized quantum correlations are robust even in the presence of environmental noise.
  • The findings have implications for understanding and utilizing quantum correlations in various quantum technologies.