Related Experiment Video
Updated: May 27, 2026

Single-molecule Manipulation of G-quadruplexes by Magnetic Tweezers
Published on: September 19, 2017
Coupling single molecule magnets to ferromagnetic substrates
A Lodi Rizzini1, C Krull, T Balashov
1Catalan Institute of Nanotechnology (ICN-CIN2), UAB Campus, E-08193 Barcelona, Spain.
Abstract:
We investigate the interaction of TbPc(2) single molecule magnets (SMMs) with ferromagnetic Ni substrates. Using element-resolved x-ray magnetic circular dichroism, we show that TbPc(2) couples antiferromagnetically to Ni films through ligand-mediated superexchange. This coupling is strongly anisotropic and can be manipulated by doping the interface with electron acceptor or donor atoms. We observe that the relative orientation of the substrate and molecule anisotropy axes critically affects the SMM magnetic behavior. TbPc(2) complexes deposited on perpendicularly magnetized Ni films exhibit enhanced magnetic remanence compared to SMMs in the bulk. Contrary to paramagnetic molecules pinned to a ferromagnetic support layer, we find that TbPc(2) can be magnetized parallel or antiparallel to the substrate, opening the possibility to exploit SMMs in spin valve devices.
Related Concept Videos
Ferromagnetism
Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
¹H NMR: Long-Range Coupling
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
Double Resonance Techniques: Overview
Spin decoupling is usually achieved by...
NMR Spectroscopy: Spin–Spin Coupling
Applications Of NMR In Biology
The...
