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Asymmetric stochastic localization in geometry controlled kinetics.

Debasish Mondal1, Deb Shankar Ray

  • 1Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700032, India. juniordebasish@gmail.com

The Journal of Chemical Physics
|November 25, 2011
PubMed
Summary

We studied Brownian particle motion in a bilobal enclosure. Correlated noise forces broke symmetry, causing particles to favor one lobe due to entropic diffusion.

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Area of Science:

  • Statistical Physics
  • Soft Matter Physics

Background:

  • Brownian motion describes random particle movement.
  • Confined systems exhibit unique behaviors.
  • Entropic potentials arise from geometric constraints.

Purpose of the Study:

  • Investigate Brownian particle dynamics in a 2D bilobal enclosure.
  • Analyze the effect of correlated additive and multiplicative noise.
  • Understand symmetry breaking and population localization.

Main Methods:

  • Simulating Brownian particle motion.
  • Introducing correlated additive and multiplicative noise forces.
  • Analyzing stationary state distributions.
  • Developing a two-state model for entropic diffusion.

Main Results:

  • Varying enclosure cross-section creates an effective 1D entropic potential.
  • Correlation between noise forces breaks entropic stability symmetry.
  • Particles exhibit asymmetric population localization in the two lobes.
  • The two-state model successfully explains the observed asymmetry.

Conclusions:

  • Correlated noise is crucial for controlling particle distribution in confined systems.
  • Entropic diffusion can lead to symmetry breaking and asymmetric localization.
  • This work provides insights into manipulating particle behavior in complex environments.