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Updated: May 26, 2026

Probing the Structure and Dynamics of Interfacial Water with Scanning Tunneling Microscopy and Spectroscopy
Published on: May 27, 2018
Vibrational dynamics of the bending mode of water interacting with ions
1FOM Institute AMOLF, Science Park 104, 1098 XG Amsterdam, The Netherlands. piatkowski@amolf.nl
Abstract:
We studied the vibrational relaxation dynamics of the bending mode (ν(2)) of the H(2)O water molecules in the presence of different salts (LiCl, LiBr, LiI, NaI, CsI, NaClO(4), and NaBF(4)). The linear and nonlinear spectra of the bending mode show distinct responses of water molecules hydrating the anions. We observe that the bending mode of water molecules that are hydrogen-bonded to an anion exhibits much slower relaxation rates (T(1)~1ps) than water molecules that are hydrogen-bonded to other water molecules (T(1)=400 fs). We find that the effect of the anion on the absorption spectrum and relaxation time constant of the water bending mode is not only determined by the strength of the hydrogen-bond interaction but also by the shape of the anion.
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