Electrochemical detection of hydrazine using a highly sensitive nanoporous gold electrode

A facile alloy-dealloy technique performed in aqueous media was employed to prepare a nanoporous gold (NPG) electrode that demonstrated extremely high sensitivity toward hydrazine oxidation. An Ag(∼60)Au(∼40) alloy was electrodeposited at a constant potential on sequentially Cr- and Au-deposited indium tin oxide (Au/Cr/ITO) from a bath that contained sulfuric acid, thiourea, HAuCl(4)·3H(2)O, and AgNO(3). The dealloying step was performed in concentrated HNO(3), where Ag in the alloy was selectively oxidized to leave the NPG structure. The NPG electrode was employed to study the hydrazine oxidation in basic phosphate buffer solution (PBS), and the results were compared with those obtained using the gold nanoparticle (AuNP)-modified ITO (AuNP/ITO) electrode. The NPG electrode demonstrated an unusual surface-confined behavior, which probably resulted from the thin-layer characteristics of the nano-pores. Hydrazine was detected by hydrodynamic chronoamperometry (HCA) at +0.2V (vs. Ag/AgCl). The steady-state oxidative current exhibited a linear dependence on the hydrazine concentration in the concentration range of 5.00 nM-2.05 mM, and the detection limit was 4.37 nM (σ=3). This detection limit is the lower than the detection limits reported in the current literature concerning the electrochemical detection of hydrazine. The NPG electrode indeed demonstrates greater stability after hydrazine detection than the AuNP/ITO electrode.