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Updated: May 26, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Two-dimensional assembly of tetrahedral chalcogenide clusters with tetrakis(imidazolyl)borate ligands
Ziyi Chen1, Daibing Luo, Xiuchao Luo
1College of Chemistry, Sichuan University, Chengdu, 610064, P. R. China.
Abstract:
A new two-dimensional inorganic-organic hybrid solid, formulated as Cd(17)S(4)(SPh)(25)B(im)(4) (SPh = benzenethiolate, im = imidazolate), has been synthesized under solvothermal conditions. The structure features a 6(3) network with 17-nuclear cadmium clusters linked by B(im)(4)(-) ligands. The compound is a semiconductor with the band gap of 2.66 eV and displays a green luminescence upon excitation at 390 nm.
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