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Preparation and structure of a tubular addition polymer: a true synthetic nanotube

Te-Jung Hsu1, Frank W Fowler, Joseph W Lauher

  • 1Department of Chemistry, State University of New York, Stony Brook, New York 11794-3400, USA.

Journal of the American Chemical Society
|December 16, 2011
PubMed

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Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta catalyst, high molecular...