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Updated: May 26, 2026

Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
Published on: March 12, 2015
Design and construction of endo-functionalized multiferrocenyl hexagons via coordination-driven self-assembly and
Li-Jun Chen1, Quan-Jie Li, Jiuming He
1Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, People's Republic of China.
Abstract:
The construction of a new family of endo-functionalized multiferrocenyl hexagons with various sizes via coordination-driven self-assembly is described. The structures of these novel metallacycles, containing several ferrocenyl moieties at their interior surface, are characterized by multinuclear NMR ((31)P and (1)H) spectroscopy, cold-spray ionization mass spectrometry (CSI-TOF-MS), elemental analysis, and molecular modeling. Insight into the structural and electrochemical properties of these endo-functionalized multiferrocenyl hexagons was obtained through cyclic voltammetry investigation.
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