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Updated: May 26, 2026

Facet-to-facet Linking of Shape-anisotropic Colloidal Cadmium Chalcogenide Nanostructures
Published on: August 10, 2017
(2,9-Dimethyl-1,10-phenanthroline-κN,N')diiodidocadmium
Abstract:
In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol-ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra-hedral geometry. Inversion-related mol-ecules inter-act along the c-axis direction by π-π stacking inter-actions between the phenanthroline ring systems, with centroid-centroid distances of 3.707 (9) and 3.597 (10) Å.
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