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Updated: May 26, 2026

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
Published on: October 3, 2014
trans-Carbonyl-chloridobis(tri-o-tolyl-phosphane-κP)rhodium(I)
Stefan Warsink1, Renier Koen, Andreas Roodt
1Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.
Abstract:
In the title compound, [RhCl(C(21)H(21)P)(2)(CO)], the coordination geometry around the Rh(I) atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the Rh(I) atom lies on a center of inversion. The effective cone angle Θ(E) for the title compound is 169.0 (3)°. There are no significant inter-molecular inter-actions.
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