Related Experiment Video
Updated: May 26, 2026

Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
[1,5-Bis(4-fluoro-phen-yl)thio-carbazo-nato-κN,S]phenyl-mercury(II) dichloro-methane hemisolvate
Abstract:
In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio-carbazo-nate ligands by 61.49 (10) and 67.79 (11)° in the two complex mol-ecules comprising the asymmetric unit. Important geometrical parameters include Hg-C = 2.079 (4) and 2.087 (4) Å, Hg-S = 2.3869 (10) and 2.3889 (11) Å, and C-Hg-S = 166.42 (12) and 168.09 (13)°. Weak intramolecular Hg-N bonding inter-actions of 2.589 (4) and 2.626 (4) Å are observed. In the crystal, C-H⋯Cl, C-H⋯F, C-H⋯N, C-H⋯π and π-π [centroid-centroid distances = 3.648 (3) and 3.641 (3) Å] inter-actions, create parallel planes along [101].
More Related Videos
Related Concept Videos
Electrophilic Aromatic Substitution: Fluorination and Iodination of Benzene
Preparation and Reactions of Sulfides
Hydrolysis of Chlorobenzene to Phenol: Dow Process
ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3
Diazonium Group Substitution: –OH and –H
Alkyl Halides
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...

