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Poly[aqua-{μ(3)-5-[(pyridin-2-ylmeth-yl)amino]-isophthalato-κN,N':O,O:O}cobalt(II)]

Xiao-Hong Zhu1, Xiao-Chun Cheng

  • 1Faculty of Life Science and Chemical Engineering, Huaiyin Institute of Technology, Huaian 223003, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online
|December 27, 2011
PubMed

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In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
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Isomerism in Complexes
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