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2-[(Pyridin-3-yl-amino)-meth-yl]phenol
Acta Crystallographica. Section E, Structure Reports Online
|December 27, 2011
Summary
This study details the crystal structure of a novel organic compound, C(12)H(12)N(2)O. The molecule exhibits significant twisting between aromatic rings and forms a layered structure through specific hydrogen bonding interactions.
Area of Science:
- Crystallography
- Organic Chemistry
- Supramolecular Chemistry
Background:
- Understanding molecular conformation and intermolecular interactions is crucial in crystal engineering.
- Organic compounds with amino and hydroxyl groups can participate in diverse hydrogen bonding networks.
Purpose of the Study:
- To elucidate the crystal structure and hydrogen bonding patterns of the title compound, C(12)H(12)N(2)O.
- To investigate the role of substituents in directing crystal packing and supramolecular assembly.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed to determine the three-dimensional molecular structure.
- Analysis of hydrogen bonding interactions and their influence on crystal architecture.
Main Results:
- The crystal structure reveals a significant twist (68.79°) between the aromatic rings linked by a -CH(2)-NH- group.
- The hydroxyl group acts as both a hydrogen bond donor and acceptor, forming chains along the b axis and contributing to a layered structure.
Conclusions:
- The specific arrangement of functional groups dictates the observed supramolecular architecture.
- The hydrogen bonding network in C(12)H(12)N(2)O leads to the formation of a distinct layer structure in the solid state.
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