Related Experiment Video
Updated: May 26, 2026

Facet-to-facet Linking of Shape-anisotropic Colloidal Cadmium Chalcogenide Nanostructures
Published on: August 10, 2017
Poly[(μ(2)-4,4'-bipyridine-κN:N')(μ(2)-2,2-dimeth-yl-cyclo-pentane-1,3-dicarboxyl-ato-κO,O:O,O)cadmium]
Abstract:
In the title polymeric compound, [Cd(C(9)H(12)O(4))(C(10)H(8)N(2))](n), the Cd(II) atom is located on a twofold rotation axis and is coordinated by two 4,4'-bipyridine ligands and two 2,2-dimethyl-cyclo-pentane-1,3-dicarboxyl-ate ions. The carboxyl-ate ion and the N-heterocycle both function as bridges to link adjacent Cd(II) atoms to result in the formation of a layer structure parallel to (010). The mid-point of the central C-C bond of the 4,4'-bipyridine ligand is located on an inversion center. In the crystal, the carboxyl-ate ion is disordered over a twofold rotation axis in respect of its methyl group and the cyclo-pentane ring.
More Related Videos
09:45Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
05:21The Effect of Ultraviolet Radiation on the Chemical Bath Deposition of Bis(thiourea) Cadmium Chloride Crystals and the Subsequent CdS Obtention
Published on: August 30, 2018
Related Concept Videos
Coordination Number and Geometry
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group with both...
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Valence Bond Theory
[4+2] Cycloaddition of Conjugated Dienes: Diels–Alder Reaction
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...