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6-Bromo-imidazo[1,2-a]pyridin-8-amine
Acta Crystallographica. Section E, Structure Reports Online
|January 6, 2012
Summary
This study details the crystal structure of a bromine-containing compound, revealing three unique molecules. These molecules exhibit near-planar structures and form hydrogen bonds in their crystalline state.
Area of Science:
- Crystallography
- Chemical Physics
Background:
- Understanding the solid-state structure of organic compounds is crucial for predicting their properties.
- Brominated nitrogen-containing heterocycles are important in various chemical applications.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(7)H(6)BrN(3).
- To analyze the molecular geometry and intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the crystal structure.
- Analysis of molecular planarity and hydrogen bonding networks was performed.
Main Results:
- The compound crystallizes with three independent molecules in the asymmetric unit.
- Molecules are approximately planar, with minor deviations from planarity.
- Primary amine groups exhibit pyramidal coordination.
- Intermolecular N-H⋯N hydrogen bonds link adjacent molecules in the crystal.
Conclusions:
- The crystal structure of C(7)H(6)BrN(3) has been determined.
- The hydrogen bonding patterns provide insights into the compound's solid-state behavior.
- The observed molecular geometry and interactions are characteristic of this class of compounds.
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Separation of the aromatic...
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