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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
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Published on: August 22, 2018

4-(o-Tol-yl)piperazin-1-ium chloride

Hoong-Kun Fun, Safra Izuani Jama Asik, B Chandrakantha

    Acta Crystallographica. Section E, Structure Reports Online
    |January 6, 2012
    PubMed

    Abstract:

    In the title mol-ecular salt, C(11)H(17)N(2) (+)·Cl(-), the piperazin-1-ium ring adopts a chair conformation with the aromatic ring in a pseudo-equatorial orientation. The dihedral angle between the benzene ring and the mean plane of the piperazin-1-ium ring is 51.22 (6)°. In the crystal, N-H⋯Cl hydrogen bonds link the mol-ecules into chains propagating in [100]. Weak C-H⋯π inter-actions also ocur.

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