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Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene

Aurélien Hameau1, Sabine Fuchs, Régis Laurent

  • 1CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, BP 44099, F-31077 Toulouse, France.

Beilstein Journal of Organic Chemistry
|January 13, 2012
PubMed

Keywords:
dabsyldansyldendrimerdendronfluorescence

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Aryldiazonium Salts to Azo Dyes: Diazo Coupling01:11

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.