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Calcium-amidoborane-ammine complexes: thermal decomposition of model systems

Sjoerd Harder1, Jan Spielmann, Briac Tobey

  • 1Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands. s.harder@rug.nl

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 18, 2012
PubMed

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Enamine formation involves the addition of carbonyl compounds to a secondary amine through a series of reactions. The mechanism begins with the generation of carbinolamine, a nucleophilic attack followed by several proton transfer reactions. The hydroxyl group of the carbinolamine is converted into water to make a better leaving group that can push the reaction forward by eliminating a water molecule. In enamine formation, the last step involves the abstraction of a proton from the α carbon to...
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