Related Experiment Video
Updated: May 25, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Lattice effects on the spin-crossover profile of a mononuclear manganese(III) cation
Komala Pandurangan1, Brendan Gildea, Caroline Murray
1Centre for Synthesis and Chemical Biology, School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
Abstract:
Six solvated salts of a mononuclear manganese(III) complex with a chelating hexadentate Schiff base ligand are reported. One member of the series, [MnL]PF(6)⋅0.5 CH(3)OH (1), shows a rare low-spin (LS) electronic configuration between 10-300 K. The remaining five salts, [MnL]NO(3)⋅C(2)H(5)OH(2), [MnL]BF(4)⋅C(2)H(5)OH(3), [MnL]CF(3)SO(3)⋅C(2)H(5)OH (4), [MnL]ClO(4)⋅C(2)H(5)OH (5) and [MnL]ClO(4)⋅0.5 CH(3)CN (6), all show gradual incomplete spin-crossover (SCO) behaviour. The structures of all were determined at 100 K, and also at 293 K in the case of 3-6. The LS salt [MnL]PF(6)⋅0.5 CH(3)OH is the only member of the series that does not exhibit strong hydrogen bonding. At 100 K two of the four SCO complexes (2 and 4) assemble into 1D hydrogen-bonded chains, which weaken or rupture on warming. The remaining SCO complexes 3, 5 and 6 do not form 1D hydrogen-bonded chains, but instead exhibit discrete hydrogen bonding between cation/counterion, cation/solvent or counterion/solvent and show no significant change on warming.
Related Concept Videos
Trends in Lattice Energy: Ion Size and Charge
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Lattice Energies of Ionic Crystals
Valence Bond Theory
NMR Spectroscopy: Spin–Spin Coupling
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...

