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Updated: May 25, 2026
Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
trans-Dichloridobis[dicyclo-hex-yl(4-isopropyl-phen-yl)phosphane-κP]platinum(II) acetone monosolvate
1Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, Johannesburg 2006, South Africa.
Abstract:
The title compound, [PtCl(2)(C(21)H(33)P)(2)]·C(3)H(6)O, crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment, with a P-Pt-P angle of 172.41 (3)° as the most prominent feature. Both isopropyl fragments were treated as disordered over two conformations with occupancy ratios of 0.55 (2):0.45 (2) and 0.58 (2):0.42 (2). The solvent mol-ecule was also disordered over two orientations in a 1:1 ratio. The crystal studied was a non-merohedral twin with a twin component of 32.4%.
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