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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
Ethane-1,2-diaminium (R)-2-[4-(1-carboxyl-atoeth-oxy)phen-oxy]acetate
Chang-Yue Ren1, Guang-Feng Hou, Ying-Hui Yu
1Engineering Research Center of Pesticides of Heilongjiang University, Heilongjiang University, Harbin 150050, People's Republic of China, and College of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.
Abstract:
In the title compound, C(2)H(10)N(2) (2+)·C(11)H(10)O(6) (2-), the two acetate groups of the cation form dihedral angles of 74.2 (4) and 63.9 (5)° with the central benzene ring. In the crystal, N-H⋯O hydrogen bonds link the cations and anions into layers parallel to the ab plane.
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