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Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Apical functionalization of chiral heterohelicenes

Sravan K Surampudi1, G Nagarjuna, Daiki Okamoto

  • 1Department of Chemistry, University of Massachusetts Amherst, 710 North Pleasant Street, Amherst, Massachusetts 01003, USA.

The Journal of Organic Chemistry
|January 31, 2012
PubMed
Summary

Researchers developed a new copper-catalyzed amination method for selectively functionalizing chiral bridged triarylamines. This regioselective synthesis enables the creation of complex molecules, including chiral heterohelicene homodimers.

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