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Synthetic Studies Towards MPC1001: Preparation of a β-hydroxyl-Tyrosine Derivative
Paul T Schuber1, Robert M Williams
1Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.
Tetrahedron Letters
|January 31, 2012
Abstract:
A procedure for the asymmetric synthesis of a novel β-hydroxy-α-amino acid deriverative to be used in the preparation of the natural product MPC1001 and analogs has been developed. The amino acid was efficiently prepared in six steps via a Mukaiyama aldol reaction via a diphenyloxazinone and 3-bromo-4-methoxybenzaldehyde.
