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Updated: May 25, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Ion-specific self-assembly of low-dimension aggregate structures of conjugated polymer at two-phase interface
Chunjie Zhou1, Nan Chen, Jien Yang
1CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China.
Abstract:
A novel and facile approach to manipulate the morphology of Cu(2+)-ion-specific assembly of conjugated polymer by coordinative interaction at an oil-water two-phase interface is present. The application of increasing importance is the use of π-conjugated polymers as receptors, exploiting their ability to selectively form complexes, which can obviously change the optical properties in solution and induce the formation of varied solid nano/microstructures. By this method, microtubes are formed through self-rolling of a strained ionic bilayer film at the oil/water interface.
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