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Physangulidines A, B, and C: three new antiproliferative withanolides from Physalis angulata L
Zhuang Jin1, Mark S Mashuta, Neal J Stolowich
1Department of Chemistry, University of Louisville, Louisville, Kentucky 40292, USA.
Abstract:
Bioassay-directed fractionation of the whole plant of Physalis angulata L. afforded three new antiproliferative withanolides with an unusual carbon framework: physangulidines A (1), B (2), and C (3). Structures of the three isomeric withanolides were determined by a combination of HRMS, NMR spectroscopic, and X-ray crystallographic methods. Each has shown significant antiproliferative activity against DU145 prostate cancer cells. Physangulidine A (1) was further tested against a wide range of additional cancer cell lines and found to exhibit significant antiproliferative activity.
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