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Updated: May 24, 2026

Coulomb Explosion Imaging as a Tool to Distinguish Between Stereoisomers
Published on: August 18, 2017
Two-body Coulomb explosion in methylacetylene in intense laser fields: double proton migration and proton/deuteron
Tomoya Okino1, Anri Watanabe, Huailiang Xu
1Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Abstract:
Two-body decomposition processes of methylacetylene (CH(3)CCH) and its isotopomer methyl-d(3)-acetylene (CD(3)CCH) in intense laser fields (790 nm, 40 fs, 5.0 × 10(13) W cm(-2)) are investigated by the coincidence momentum imaging (CMI). In methyl-d(3)-acetylene, a total of six decomposition pathways in which one of the C-C bonds is broken and a total of six pathways in which an atomic hydrogen ion (H(+) or D(+)) or a molecular hydrogen ion (H(2)(+), HD(+), D(3)(+), or HD(2)(+)) is ejected are identified. It is revealed from the analysis of the CMI data that the migration of two deuterons as well as the exchange between a proton and a deuteron occurs prior to the two-body decomposition of a doubly charged parent molecule.
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