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Updated: May 24, 2026
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Bis(azido-κN)(1,10-phenanthroline-κN,N')palladium(II)
1School of Applied Chemical Engineering, The Research Institute of Catalysis, Chonnam National University, Gwangju 500-757, Republic of Korea.
Abstract:
In the title complex, [Pd(N(3))(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline (phen) ligand and two N atoms from two azide anions. The azido ligands are slightly bent with bond angles of 174.8 (4) and 174.5 (5)°. The complex mol-ecules are stacked in columns along the a axis and are connected by inter-molecular C-H⋯N hydrogen bonds, forming a three-dimensional network. In the columns, numerous inter-molecular π-π inter-actions between the six-membered rings are present, the shortest ring centroid-centroid distance being 3.607 (2) Å.
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