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Related Experiment Video

Updated: May 24, 2026

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Morpholin-4-ium hydrogen l-tartrate monohydrate.

T Kishore Kumar, D Prem Anand, S Selvakumar

    Acta Crystallographica. Section E, Structure Reports Online
    |February 21, 2012
    PubMed
    Summary

    This study details the crystal structure of a morpholinium tartrate monohydrate. The morpholine ring adopts a chair conformation, forming a 3D network through hydrogen bonding interactions.

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    Area of Science:

    • Crystallography
    • Chemical Physics
    • Materials Science

    Background:

    • Understanding the hydrogen bonding networks in organic salts is crucial for predicting their physical properties.
    • Morpholine and tartrate are common functional groups with diverse applications.

    Purpose of the Study:

    • To elucidate the crystal structure of morpholinium tartrate monohydrate.
    • To analyze the hydrogen bonding interactions and network formation in the crystal.

    Main Methods:

    • Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
    • Analysis of intermolecular interactions, including hydrogen bonds, was performed.

    Main Results:

    • The morpholine ring was observed in a chair conformation.

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    Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
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  • Tartrate anions formed chains via O-H⋯O hydrogen bonds along the [101] direction.
  • A three-dimensional network was established through N-H⋯O and O-H⋯O hydrogen bonds involving morpholinium cations and water molecules.

    • Conclusions:

    • The crystal structure reveals a complex three-dimensional hydrogen-bonded network.
    • The study provides insights into the supramolecular assembly of morpholinium tartrate monohydrate.