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Updated: May 24, 2026

Estimation of Urinary Nanocrystals in Humans using Calcium Fluorophore Labeling and Nanoparticle Tracking Analysis
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Published on: February 9, 2021

Creatinium hydrogen oxalate.

A Jahubar Ali, S Athimoolam, S Asath Bahadur

    Acta Crystallographica. Section E, Structure Reports Online
    |February 21, 2012
    PubMed
    Summary
    This summary is machine-generated.

    The crystal structure of a novel compound was determined using hydrogen bonds. This analysis revealed specific arrangements of cations and anions, forming distinct molecular aggregations.

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    Area of Science:

    • Crystallography
    • Materials Science
    • Chemical Physics

    Background:

    • Understanding the crystal structure of compounds is crucial for predicting their properties.
    • Hydrogen bonding plays a significant role in stabilizing crystal lattices.

    Purpose of the Study:

    • To determine the crystal structure of the compound C(4)H(10)N(3)O(2) (+)·C(2)HO(4) (-).
    • To investigate the role of hydrogen bonds in the stabilization of the crystal structure.
    • To analyze the aggregation patterns of cations and anions within the unit cell.

    Main Methods:

    • Single-crystal X-ray diffraction was employed to elucidate the crystal structure.
    • Analysis of intermolecular interactions, specifically N-H⋯O and O-H⋯O hydrogen bonds.

    Main Results:

    • The crystal structure is stabilized by N-H⋯O and O-H⋯O hydrogen bonds.
    • Anionic oxalate (C(2)HO(4) (-)) units form C(5) chains along the c axis via O-H⋯O hydrogen bonds.
    • Cationic (C(4)H(10)N(3)O(2) (+)) units form dimers around unit cell corners, creating an R(2)(2)(14) ring motif.
    • Distinct cationic and anionic molecular aggregations were observed at specific positions within the unit cell.

    Conclusions:

    • The crystal packing is dictated by a combination of hydrogen bonding and specific cationic/anionic arrangements.
    • The observed R(2)(2)(14) ring motif and chain formation highlight the directional nature of hydrogen bonding in this system.
    • The study provides insights into the supramolecular assembly of organic salts.