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Updated: May 24, 2026
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
4-Amino-3-(4-chloro-phen-yl)-1H-1,2,4-triazole-5(4H)-thione
Sampath Natarajan1, Rita Mathews
1Department of Advanced Technology Fusion, Konkuk University, 1 Hwayang-dong, Gwangjin-gu, Seoul 143 701, Republic of Korea.
Abstract:
In the title compound, C(8)H(7)ClN(4)S, the benzene ring is statistically disordered over two conformations rotated about the Cl-C⋯C-C axis, which subtend dihedral angles of 24.7 (3) and 9.9 (2) ° with respect to the triazole ring. An intra-molecular C-H⋯N close contact occurs. In the crystal, N-H⋯N and N-H⋯S hydrogen bonds link the mol-ecules into (001) sheets: R(2) (2)(8) and R(2) (2)(10) graph-set motifs result. Weak C-H⋯N hydrogen bonds and aromatic π-π stacking inter-actions [shortest centroid-centroid separation = 3.681 (7) Å] complete the structure.
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