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Updated: May 24, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
1-[Amino-(4-chloro-phen-yl)meth-yl]-6-bromo-naphthalen-2-ol
Abstract:
In the title compound, C(17)H(13)BrClNO, the dihedral angle between the naphthol ring system and the chloro-benzene ring is 76.59 (11)°. This twisted conformation is supported by an intra-molecular O-H⋯N hydrogen bond. In the crystal, [100] chains arise, with adjacent mol-ecules linked by an N-H⋯O hydrogen bond, a C-H⋯π inter-action and an aromatic π-π stacking contact [centroid-to-centroid separation = 3.783 (2) Å]. Weak C-H⋯O inter-actions also occur.
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