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Updated: May 24, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Macroscopic nucleation phenomena in continuum media with long-range interactions
Masamichi Nishino1, Cristian Enachescu, Seiji Miyashita
1Computational Materials Science Center, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047, Japan. nishino.masamichi@nims.go
Abstract:
Nucleation, commonly associated with discontinuous transformations between metastable and stable phases, is crucial in fields as diverse as atmospheric science and nanoscale electronics. Traditionally, it is considered a microscopic process (at most nano-meter), implying the formation of a microscopic nucleus of the stable phase. Here we show for the first time, that considering long-range interactions mediated by elastic distortions, nucleation can be a macroscopic process, with the size of the critical nucleus proportional to the total system size. This provides a new concept of "macroscopic barrier-crossing nucleation". We demonstrate the effect in molecular dynamics simulations of a model spin-crossover system with two molecular states of different sizes, causing elastic distortions.
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