Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Shu-Feng Zhao1, Huan Wang, Yang-Chun Lan

  • 1Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China.

Journal of Electroanalytical Chemistry (Lausanne, Switzerland)
|February 28, 2012
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Design and evaluation of injectable niclosamide nanocrystals prepared by wet media milling technique.

Drug development and industrial pharmacy·2014
Same author

Effects of valproic Acid on axonal regeneration and recovery of motor function after peripheral nerve injury in the rat.

The archives of bone and joint surgery·2014
Same author

Downregulation of leaf flavin content induces early flowering and photoperiod gene expression in Arabidopsis.

BMC plant biology·2014
Same author

Fluoride affects calcium homeostasis and osteogenic transcription factor expressions through L-type calcium channels in osteoblast cell line.

Biological trace element research·2014
Same author

Malignant melanoma of the vagina: A case report and review of the literature.

Oncology letters·2014
Same author

Synthesis and reactivity of new aminophenolate complexes of nickel.

Molecules (Basel, Switzerland)·2014
Same journal

Understanding Baseline Drift in Laser-Induced Graphene Electrodes and Its Impact on Heavy Metal Detection by Anodic Stripping Voltammetry: Comparison with Glassy Carbon Electrode.

Journal of electroanalytical chemistry (Lausanne, Switzerland)·2026
Same journal

Recycling spent masks to fabricate flexible hard carbon anode toward advanced sodium energy storage.

Journal of electroanalytical chemistry (Lausanne, Switzerland)·2023
Same journal

Facile fabrication of hierarchically nanostructured gold electrode for bio-electrochemical applications.

Journal of electroanalytical chemistry (Lausanne, Switzerland)·2022
Same journal

Ferrocene-Grafted Carbon Nanotubes for Sensitive Non-Enzymatic Electrochemical Detection of Hydrogen Peroxide.

Journal of electroanalytical chemistry (Lausanne, Switzerland)·2022
Same journal

Nickel-based electrochemical sensor with a wide detection range for measuring hydroxyl ions and pH sensing.

Journal of electroanalytical chemistry (Lausanne, Switzerland)·2021
Same journal

Preconcentration mechanism of trivalent lanthanum on eQCM electrodes in the presence of α-hydroxy isobutyric acid.

Journal of electroanalytical chemistry (Lausanne, Switzerland)·2021
See all related articles

Electrocarboxylation of benzophenones using a magnesium anode yields benzilic acids. Reaction efficiency depends heavily on solvent, electrolyte, cathode, current density, temperature, and substrate.

Area of Science:

  • Electrochemistry
  • Organic Synthesis

Background:

  • Benzophenones are versatile organic compounds.
  • Carboxylation reactions are crucial in organic synthesis.

Purpose of the Study:

  • To investigate the electrocarboxylation of benzophenones.
  • To determine factors influencing carboxylation yield.

Main Methods:

  • Galvanostatic electrolysis in aprotic solvents.
  • Use of a magnesium sacrificial anode in an undivided cell.
  • Systematic variation of operational and intrinsic parameters.

Main Results:

  • Successful electrocarboxylation of various benzophenones to benzilic acids.
  • Yields are highly sensitive to solvent choice.

Related Experiment Videos

  • Cathode material, current density, temperature, and substrate structure significantly impact reaction outcomes.

    • Conclusions:

    • Electrocarboxylation offers a viable route to benzilic acids.
    • Optimizing reaction conditions is key for efficient synthesis.
    • Further studies can refine this electrochemical method.