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Carbon(sp(3))-fluorine bond-forming reductive elimination from palladium(IV) complexes

Joy M Racowski1, J Brannon Gary, Melanie S Sanford

  • 1Department of Chemistry, University of Michigan, Ann Arbor, 48109, USA.

Angewandte Chemie (International Ed. in English)
|March 1, 2012
PubMed
Summary

New palladium(IV)-fluoride complexes enable selective C(sp(3))-F coupling reactions. These complexes show remarkable water insensitivity, simplifying synthetic procedures and expanding catalytic applications in fluorination chemistry.

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