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Synthesis of fluorinated oxadiazoles with gelation and oxygen storage ability

Antonio Palumbo Piccionello1, Annalisa Guarcello, Alessandro Calabrese

  • 1Dipartimento di Scienze e Tecnologie Molecolari e Biomolecolari - Sez. Chimica Organica E. Paternò, Università degli Studi di Palermo, Viale delle Scienze - Parco d'Orleans II, Ed. 17, I-90128, Palermo, Italy. antonio.palumbopiccionello@unipa.it

Organic & Biomolecular Chemistry
|March 8, 2012
PubMed

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Overview
Epoxides result from alkene oxidation, which can be achieved by a) air, b) peroxy acids, c) hypochlorous acids, and d) halohydrin cyclization.
Epoxidation with Peroxy Acids
Epoxidation of alkenes via oxidation with peroxy acids involves the conversion of a carbon–carbon double bond to an epoxide using the oxidizing agent meta-chloroperoxybenzoic acid, commonly known as MCPBA. Since the O–O bond of peroxy acids is very weak, the addition of electrophilic oxygen of peroxy acids to...